Internal energy refers to the total energy contained within a material, including both kinetic and potential energy of its particles. Changes in temperature or state of matter are influenced by alterations in this internal energy. The amount of energy needed for such changes is determined by the material’s characteristics, specifically its ‘heat capacity’—the energy required to change its temperature—and ‘latent heat’—the energy absorbed or released during a change in its state.
Internal energy is a concept that can be observed in various aspects of daily life. Here are some examples:
When a material is heated or cooled, its particles undergo two key changes. Firstly, chemical bonds may form, break, or stretch, altering the material’s chemical energy storage. Simultaneously, the material heats up or cools down as particles gain or lose speed, affecting its thermal energy storage.
The change in internal energy (ΔU) of a system is related to the heat (Q) added to or removed from the system and the work (W) done by or on the system. The equation is given by the first law of thermodynamics:
ΔU=Q−W
Here:
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